Mechanistic Studies on NaHCO3 Hydrogenation and HCOOH Dehydrogenation Reactions Catalysed by a FeII Linear Tetraphosphine Complex
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چکیده
منابع مشابه
Catalytic hydrogenation of alkenes on acidic zeolites: Mechanistic connections to monomolecular alkane dehydrogenation reactions
Brønsted acid sites in zeolites (H-FER, H-MFI, H-MOR) selectively hydrogenate alkenes in excess H2 at high temperatures (>700 K) and at rates proportional to alkene and H2 pressures. This kinetic behavior and the De Donder equations for non-equilibrium thermodynamics show that, even away from equilibrium, alkene hydrogenation and monomolecular alkane dehydrogenation occur on predominantly uncov...
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The lipases from porcine pancreas and Cundida cylindracea have been successfully used in carrying out simple, efficient and potentially useful biotransformations on diols and peracetylated polyphenolic esters. It has been observed that the esterification reactions on 1,Zdiols are highly regiaselective and the primary hydroxyl group is exclusively esterified over the one at the secondary positio...
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The dehydrogenation of piperidine has been studied and found to have an order of -1.5 with respect to the hydrogen partial pressure. By combining these results with those obtained for pyridine hydrogenation on the same catalyst a complete rate equation for piperidine dehydrogenation together with the stoichiometric number of the rate-determining step of these reactions could be derived. This nu...
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چکیده ندارد.
15 صفحه اولMechanistic insights into boron-catalysed direct amidation reactions
Centre for Sustainable Chemical Process University, Science Site, South Road, Durha durham.ac.uk Department of Chemistry, University Coll WC1H 0AJ, UK Department of Chemistry, Durham Univer DH1 3LE, UK Department of Chemistry, Imperial Colle London, SW7 2AZ, UK † Electronic supplementary information spectra, computational data and ES 1551614–1551624 and 1563948–1563950. CIF or other electronic ...
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2018
ISSN: 0947-6539
DOI: 10.1002/chem.201704927